AP Chemistry - Important Redox agents
30 flashcards · Other · by luckydog789 (harrison holbrook)
Important Oxidizing Agents (these are reduced)
Formed in reaction
MnO4−1MnO_4^{-1}MnO4−1 (acid solution)
Mn+2Mn^{+2}Mn+2
MnO4−1MnO_4^{-1}MnO4−1 (basic solution)
MnO2MnO_2MnO2
MnO2MnO_2MnO2 (acid solution)
Mn+2Mn^{+2}Mn+2
Cr2O7−2Cr_2O_7^{-2}Cr2O7−2 (acid solution)
Cr+3Cr^{+3}Cr+3
CrO4−2CrO_4^{-2}CrO4−2 (basic solution)
Cr+3Cr^{+3}Cr+3
HNO3HNO_3HNO3 , concentrated
NO2NO_2NO2
HNO3HNO_3HNO3 , dilute
NONONO
H2SO4H_2SO_4H2SO4 , hot concentrated
SO2SO_2SO2
Metallic Ions (ex. Fe+3Fe^{+3}Fe+3 )
Metallous Ions (ex. Fe+2Fe^{+2}Fe+2 )
Free Halogens (ex. Cl2Cl_2Cl2 )
Halide Ions (ex. 2Cl−12Cl^{-1}2Cl−1 )
HClO4HClO_4HClO4
Cl−1Cl^{-1}Cl−1
Na2O2Na_2O_2Na2O2
OH−1OH^{-1}OH−1
H2O2H_2O_2H2O2
H2OH_2OH2O
Perhalates (ex. ClO4−1ClO_4^{-1}ClO4−1 ), halates (ex. ClO3−1ClO_3^{-1}ClO3−1 ), halites (ex. ClO2−1ClO_2^{-1}ClO2−1 )
Halogens (ex. Cl2Cl_2Cl2 )
Important Reducing agents (these are oxidized)
Formed in reaction
Halide ions (ex. 2Cl−12Cl^{-1}2Cl−1 )
Halogens (ex. Cl2Cl_2Cl2 )
Free metals (ex. FeFeFe )
Metal ions, usually of highest charge (ex. Fe+3Fe^{+3}Fe+3 )
Metallous ions (ex. Fe+2Fe^{+2}Fe+2 )
Metallic ions (ex. Fe+3Fe^{+3}Fe+3 )
Sulfite ions (ex. SO3−2SO_3^{-2}SO3−2 ), SO2SO_2SO2 gas
SO4−2SO_4^{-2}SO4−2
Free halogens, dilute basic solution (ex. ClClCl )
Hypohalite ions (ex. ClO−1ClO^{-1}ClO−1 )
Free halogens, concentrated basic solution (ex. ClClCl )
Halate ions (ex. ClO3−1ClO_3^{-1}ClO3−1 )
C2O4−2C_2O_4^{-2}C2O4−2
CO2CO_2CO2
NO2−1NO_2^{-1}NO2−1
NO3−1NO_3^{-1}NO3−1
Sn+2Sn^{+2}Sn+2
Sn+4Sn^{+4}Sn+4
H2O2H_2O_2H2O2
O2O_2O2
Misc rules
rule
Chromium
Dichromate to Cr+3Cr^{+3}Cr+3 in acid solution; chromate to Cr(OH)3Cr(OH)_3Cr(OH)3 is basic solution. Dichromate ion can turn into chromate in basic solution, and chromate ion can turn into dichromate ion in acidic solution (note: this is not redox - the CrCrCr retains a constant +6+6+6 charge)
Oxygen
Hydrogen peroxide can act as an oxidizing agent (reduced to water) and a reducing agent (oxidized to oxygen gas)
Nitrogen
Nitrate ion is an oxidizing agent only in acid solution. The reduction product is NONONO .