Chp 3: Structure of Crystalline Solids
20 flashcards · Other · by Rob House
Location of dense and random packing in the energy well graph (r_o, E_0)
Name the three structures
Crystalline , Noncrystalline ( also called Amorphous)
The most common metallic crystal structures are
FCC, BCC, and HCP
Coordination number and atomic packing factor are the same for both ____ & _____ crystal structures
FCC and HCP
Noncrystalline
• atoms have no periodic packing occurs for: - complex structures , - rapid cooling
isotropic vs anisotropic
hank green video
unit cell
the basic structural unit of a crystal structure Generally defined in terms of positions of atom within a parallel piped volume shape
lattice
the regular geometric arrangement of points in crystal space
Metallic Crystal Structures how packed are they & why
Tend to be densely packed. Reasons for dense packing: - Typically, only one element is present, so all atomic radii are the same. -Metallic bonding is not directional. - Nearest neighbor distances tend to be small in order to lower bond energy. - Electron cloud shields cores from each other. • Metals have the simplest crystal structures.
3 cubic crystal structures
SC , BCC , FCC
Atoms per unit cell
SC =1 BCC =2 FCC=4
Single crystal
monocrystalline a crystalline solid for which the periodic and repeated atomic pattern extends throughout the entry without interruption
Polycrystal
crystalline material composed of >_ 2 *something*
What causes density in material classes
packing density
what structures have the highest packing factor
TCC and BCC
Select true or false: Low-angle grain boundaries have higher grain boundary energy when compared to that of high-angle grain boundaries.
false
Polymorphism (or allotropy)
Two or more distinct crystal structures for the same material
Crystalline
atoms pack in periodic, 3D arrays typical of -metals, many ceramics, some polymers
Densities of Material Classes
Metals have... • close-packing (metallic bonding) • often large atomic masses Ceramics have... • less dense packing • often lighter elements Polymers have... • low packing density (often amorphous) • lighter elements (C,H,O)
single crystal vs polycrystal